Praise be to Allah.
If your brother is poor and is entitled to zakaah, then it is permissible for you to give him some of the charity funds that are with you (if he is from the same area that was specified by the donors), without stipulating any conditions. You should not take that to replace the money that you gave to him, but if he gives it to you of his own free will then it is o.k. for you to take it.
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