Praise be to Allah.
What you are doing for the family of your absent relative is good and is to be appreciated, because taking care of the weak by meeting their needs is a righteous deed. But it is not permissible for you to be alone with the wife, because she is a stranger (non-mahram) to you, and it is not permissible for her to uncover her face in front of you, because you are not one of her mahrams.
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